Search results for "nanoparticle polymer composites"

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Orientation and Dynamics of ZnO Nanorod Liquid Crystals in Electric Fields.

2010

ZnO nanorod polymer hybrids (i.e., ZnO nanorods coated with a block copolymer with a short anchor block (dopamine) and a longer solubilizing block of polystyrene (PS)) form liquid crystalline (LC) phases if they are dispersed at high concentration e.g., in a PS oligomer matrix. Due to the high mobility of the low T(g)-matrix the nanorod polymer hybrids show a switching behavior under an applied AC electric field. Hence, the orientation of the nanorod mesogens can be changed from planar (parallel to the substrate) to homeotropic (perpendicular) in full analogy to the switching of low molecular liquid crystals in an electric field. Dielectric measurements show that such a switching is mainly …

Phase transitionMaterials sciencePolymers and PlasticsHomeotropic alignmentDielectricpolystyrenesemiconducting nanorodspressureliquid crystalsLiquid crystalElectric fieldnanostructuresPolymer chemistryMaterials Chemistryarraysnanoparticle polymer compositespolymerschemistry.chemical_classificationbehaviorbusiness.industryOrganic ChemistryPolymermatrixelectric fieldblock copolymersDipolechemistryOptoelectronicsNanorodphasesbusinesscharge-transportMacromolecular rapid communications
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